To obtain a hard and longlasting paint film one must use some metal soaps in the
range of 0.1 to 1 %. phr.
Those metal soaps are containing the following metals: AI, Ba, Ca, Ce, Co, Fe, Li,
MG, Pb, Zn and Zr. Every metal soap effects the binding system in a different way
and the metering has to be taken in consideration.
Further more those metal soaps
must not dissolve in water. Between those soaps cobalt, lead, manganese, iron
and cerium are considered as "active" driers, calcium, zinc and zirconium soaps
are considered as "secondary" driers.
When an active drier is used in conjunction
with a secondary drier we can talk of a "synergetic" effect.
To put in a simple way the sum of 1 +1 is bigger than 2. cobalt and mangenese
soaps are oxidizing the surface of the paint film to give a hard finish. The lead soaps
are crosslinking the binder to complete the polimerisation of the system.